Fray Symposium - Electrochemical Corrosion Of Niquel In Sodium Chloride –sulfuric Acid Solutions At Different Concentration Ratios Using The Polarization Resistance Method
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2011-Sustainable Industrial Processing Summit
SIPS2011 Volume 3: Molten Salts & Ionic Liquids 2011

Editors:Florian K
Publisher:Flogen Star OUTREACH
Publication Year:2012
Pages:630 pages
ISBN:978-0-9879917-2-0
ISSN:2291-1227 (Metals and Materials Processing in a Clean Environment Series)

    Electrochemical Corrosion Of Niquel In Sodium Chloride –sulfuric Acid Solutions At Different Concentration Ratios Using The Polarization Resistance Method

    Baldemar Martinez1; Angélica Oropeza Amador1;
    1INSTITUTO POLITECNICO NACIONAL, México D.F., Mexico;
    Type of Paper: Regular
    Id Paper: 262
    Topic: 6

    Abstract:

    Specimens of Ni were conditioned in the test piece with a work area of 0.2 cm2, each one of them was polished and using as work electrode , graphite electrode and platinum electrode were used as reference electrode and counter electrode respectively.The work electrode was changing each test. The concentration ratios were 1N NaCl, 1N NaCl : 0.8N H2SO4 and 1N NaCl : 1N H2SO4 with the volume ratio 1:1 in all cases. The presence of H2SO4 increase the corrosion rate. The corrosion current intensity was determinated by polarization resistance method.The scanning rate was 2 mV per second. Due to the acid medium provides favorable conditions to the oxide film formed on the niquel surface become in a no resistance film, which is broke out, and consequently exist a pitting surface. The calculation showed a considerable increasing corrosion rate with the acid enviroment; however the pH plays an important role since it has a strong relation with the H2SO4 concentration.

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    Martinez B and Oropeza Amador A. Electrochemical Corrosion Of Niquel In Sodium Chloride –sulfuric Acid Solutions At Different Concentration Ratios Using The Polarization Resistance Method. In: Florian K, editors. Sustainable Industrial Processing Summit SIPS2011 Volume 3: Molten Salts & Ionic Liquids 2011. Volume 3. Montreal(Canada): FLOGEN Star Outreach;2012. p..